期刊
MOLECULES
卷 24, 期 21, 页码 -出版社
MDPI
DOI: 10.3390/molecules24213838
关键词
amides; nitrile hydrolysis; agro-waste; green reaction medium
资金
- National Natural Science Foundation of China [21572195, 21702175]
- Tianshan Cedar Project of Xinjiang Uygur Autonomous Region [2017XS16]
- Scientific and Technological Innovation Leading Talent Reserve of Xinjiang Uygur Autonomous Region [wr2016cx0145]
- Natural Science Foundation of Xinjiang University [BS160219]
The hydration of nitriles to amides in a water extract of pomelo peel ash (WEPPA) was realized with moderate to excellent yields without using external transition metals, bases or organic solvents. This reaction features a broad substrate scope, wide functional group tolerance, prominent chemoselectivity, and good reusability. Notably, a magnification experiment in this bio-based solvent at 100 mmol further demonstrated its practicability.
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