期刊
MICROCHIMICA ACTA
卷 186, 期 11, 页码 -出版社
SPRINGER WIEN
DOI: 10.1007/s00604-019-3869-8
关键词
Multicomponent nanomaterial; Hybrid materials; Nanomaterials synthesis; Macrocyclic hosts; Host-guest interaction; Molecular recognition; Functionalized pillar[5]arene; Supramolecular sensor; Sensing platform; Electrochemical detection
资金
- Basic Research Project of Science and Technology Commission of Chongqing [cstc2017jcyjA0656, cstc2017jcyjAX0031]
- Agricultural Joint Special Key Project in Yunnan Province [2018FG001-006]
- National Natural Science Foundation of China [21864024]
- Program for Innovation Team Building at Institutions of Higher Education in Chongqing, China [CXTDX201601039]
An ultrasensitive and highly selective electrochemical method is described for the determination of dopamine (DA). It is based on the use of a multi-functional nanomaterial composed of water-soluble pillar[5]arene (WP5), dihydroxylatopillar[5]arene (2HP5)-modified gold nanoparticles (GNPs), and graphitic carbon nitride (g-C3N4), with an architecture of type 2HP5@GNP@WP5@g-C3N4. The modified GNPs were prepared in the presence of 2HP5 that acts as reducing agent and stabilizer in the formation of GNPs. 2HP5@GNP acts as an electrocatalyst in sensing DA. The WP5@g-C3N4 nanocomposite is obtained by pi interaction between WP5 and g-C3N4 after sonication in the presence of WP5. The composite serves as a host for recognition and gathering DA on the surface of the electrode. The host-guest recognition mechanism between WP5 and DA is studied by H-1 NMR and UV-vis. The electrode, best operated at a working potential of 0.18 V (vs. SCE), works in the concentration range of 0.012-5.0 mu M DA and has a 4 nM detection limit.
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