期刊
MACROMOLECULES
卷 52, 期 21, 页码 8103-8113出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.9b01511
关键词
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资金
- Centre National de la Recherche Scientifique
- Universite de Toulouse
- Agence Nationale de la Recherche [ANR CE6-CYCLOOP]
- CAMPUS France
A dual catalyst associating InCl3 and triethylamine was found to promote controlled ring-opening polymerization of epsilon-decalactone (epsilon-DL), a monomer derived from sustainable resources. Polydecalactones (PDL) of well-defined structures with M-n up to 30 000 g/mol (D approximate to 1.2) have been obtained free of catalytic residues under mild conditions (toluene, 3M, 60 degrees C, 1-20 h). Besides the typical ester end- capped PDLs, amide end groups have been installed thanks to the ability of the dual catalyst to perform with primary amines as initiators. Block PDL-b-PCL/PCL-b-PDL and random P(DL-r-CL) copolymers have been also prepared by sequential and simultaneous ROP with epsilon-caprolactone, respectively. The absence of undesirable transesterifications reactions, as apparent from NMR, SEC, and DSC analyses, enable the preparation of well-defined copolymers.
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