期刊
LANGMUIR
卷 35, 期 48, 页码 15948-15959出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.langmuir.9b02161
关键词
-
资金
- National Science Foundation [DMR-1411144, PHY-1748958]
- Simons Foundation
The effects of realistic roughness and elasticity on the interactions between charged silica spheres are studied as a function of surface potential, screening length, interfacial energy, and roughness. The repulsive force F-rep that must be overcome to bring charged spheres into contact is relatively insensitive to elasticity unless spheres are hundreds of times softer than silica. F-rep is also insensitive to roughness and interfacial energy. In contrast, roughness has a large effect on the binding energy of spheres and the force F-sep to separate them. Both are lowered by 1 to 2 orders of magnitude by the measured surface roughness of less than 1 nm on 1 mu m silica spheres. The reason is that interactions between rigid spheres are dominated by the highest surface peaks rather than the entire spherical surface. Elasticity can increase the pull-off force of rough spheres by a factor of 2 or more because additional surface area can be brought into contact. The implications of these results for shear-thickening transitions are discussed.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据