期刊
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
卷 39, 期 14, 页码 4429-4434出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2019.06.024
关键词
CeO2; Selective plane; Sintering; Solid oxide fuel cells
资金
- National Natural Science Foundation of China [51602238]
- Natural Science Foundation of Shandong Province [ZR2018JL017]
- China Postdoctoral Science Foundation [2017M622139]
- Qingdao Postdoctoral Application Research
- Startup Funding for Talents at Qingdao University [41117010097]
- Thousand Talents Plan
- World-Class Discipline Program of Shandong Province
- Taishan Scholar's Advantageous and Distinctive Discipline Program of Shandong Province
- Australian Research Council (ARC) [FL170110001]
CeO2 nanocubes with (100) surface orientation are successfully synthesized and found to facilitate the sinterability of CeO2 material. The CeO2 nanocubes show a much-improved sinterability relative to CeO2 nanoparticles prepared by the conventional citric-nitrate method. The nanocubes can be successfully sintered at a relatively low temperature of 1200 degrees C without using any sintering aids. In contrast, a pellet using conventional CeO2 nano powder obtained from the conventional citric-nitrate method can be densified only after sintering at 1400 degrees C, which is 200 degrees C higher than that for the CeO2 nanocube sintering, although the starting particle size of both CeO2 samples is similar. Density functional theory indicates that the surface energy of the (100) plane is significantly higher than that of the (111) plane, which is the more typical surface presentation of conventional CeO2 particles. This high surface energy allows fast growth of the CeO2 nanocubes during sintering, contributing to their improved sinterability.
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