期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 49, 页码 19246-19251出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b10883
关键词
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资金
- NSFC [21425205, 21672067, 21690063]
- 973 Program [2015CB856600]
- Program of Eastern Scholar at Shanghai Institutions of Higher Learning
- Innovative Research Team of Ministry of Education
The first palladium-catalyzed asymmetric Heck reaction between aryl triflates and alkynes to give trisubstituted allenes with high er under mild reaction conditions is described. The key to the success is the discovery and fine-tuning of the different N-substituents of Xu-Phos, which ensure the enantioselectivity and reactivity. Synthetic transformation of the chiral allenes with high chirality transfer was also demonstrated.
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