期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 50, 页码 19611-19615出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b12529
关键词
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资金
- JSPS KAKENHI [15H05756, 18H04648, 19K15562]
- JST ACT-C [JPMJCR12Z9]
- Yazaki Memorial Foundation for Science and Technology
- Naohiko Fukuoka Memorial Foundation
- ENEOS Hydrogen Trust Fund
- Grants-in-Aid for Scientific Research [18H04648] Funding Source: KAKEN
A photoinduced carboxylation reaction of benzylic and aliphatic C-H bonds with CO2 is developed. Toluene derivatives capture gaseous CO2 at the benzylic position to produce phenylacetic acid derivatives when irradiated with UV light in the presence of an aromatic ketone, a nickel complex, and potassium tert-butoxide. Cyclohexane reacts with CO2 to furnish cyclohexanecarboxylic acid under analogous reaction conditions. The present photoinduced carboxylation reaction provides a direct access from readily available hydrocarbons to the corresponding carboxylic acids with one carbon extension.
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