期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 48, 页码 18949-18953出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b10741
关键词
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资金
- European Research Council [695009]
- UK Engineering and Physical Sciences Research Council [EPSRC EP/P027067/1]
- Univ. of Cambridge
- EPSRC [EP/M008258/1, EP/P027067/1] Funding Source: UKRI
Here we report a new supramolecular strategy for the selective separation of specific polycyclic aromatic hydrocarbons (PAHs) from mixtures. The use of a triethylene glycol-functionalized formylpyridine subcomponent allowed the construction of an Fe-4(II) L-4 tetrahedron 1 that was capable of transferring between water and nitromethane layers, driven by anion metathesis. Cage 1 selectively encapsulated coronene from among a mixture of eight different types of PAHs in nitromethane, bringing it into a new nitromethane phase by transiting through an intermediate water phase. The bound coronene was released from 1 upon addition of benzene, and both the cage and the purified coronene could be separated via further phase separation.
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