期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 42, 页码 16605-16609出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b09025
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资金
- Australian Research Council (ARC)
- Leopoldina Fellowship Programme, German National Academy of Sciences Leopoldina [LPDS 2017 05]
- ARC
- Evonik Industries
We introduce the hybrid copolymerization of two disparate monomer classes (vinyl monomers and ring-strained cyclic olefins) via living photopolymerization. The living character of the polymerization technique (metal-free photo-ROMP) is demonstrated by consecutive chain-extensions. Further, we propose a mechanism for the copolymerization and analyze the copolymer structure in detail by high-resolution mass spectrometry.
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