期刊
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
卷 323, 期 1, 页码 317-327出版社
SPRINGER
DOI: 10.1007/s10967-019-06888-w
关键词
Hierarchically porous Cu-BTC; Facile synthesis; Uranium(VI) removal; High uptake and removal efficiency
资金
- Natural Science Foundation of Hunan Province [2019JJ60003]
Metal-organic frameworks (MOFs) are promising adsorbents for extraction of uranium(VI) due to their high surface area and abundant active site. However, the smaller pore size (< 2 nm) and harsh synthesis conditions (e.g., high temperature and pressure) severely hinder MOFs practical applications in some cases. Herein, we developed a simple and facile method to prepare hierarchically porous Cu-BTC that contained micropores, mesopores and macropores. The as-synthesized hierarchically porous Cu-BTC showed high uptake capacity (406.9 mg g(-1)) and removal efficiency (99.7%) in the capture of uranium(VI) from an aqueous solution. Thermodynamics results indicate the spontaneous nature of uranium(VI) adsorption process onto hierarchically porous Cu-BTC. In addition, Langmuir isotherm and pseudo-second-order models were found to be more suitable in describing the adsorption process of uranium(VI) than those of Freundlich and pseudo-first-order models. These results indicate that hierarchically porous MOFs obtained from rapid room-temperature synthesis are promising adsorbents for the removal of uranium(VI) from aqueous solutions.
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