期刊
JOURNAL OF POWER SOURCES
卷 441, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2019.227172
关键词
SnOx/C; Composite; Commercial nanoparticles; Gelatination; Lithium-ion storage
资金
- National Natural Science Foundation of China [21871005, 21471006]
- Program for Innovative Research Team of Anhui Education Committee
- Research Foundation for Science and Technology Leaders and Candidates of Anhui Province
More than 200% volume change is the major restriction for the practical application of Sn-based anode materials in lithium-ion batteries. In order to prepare carbon-coated structure by a facile, low-cost, facile and common method, the solubility-dependent gelatination of carboxylated chitosan is developed for the precursors of N-doped SnOx/C composites with commercial SnO2 nanoparticles as Sn source. The phase, porosity and ratio of Sn/C of the composites can be easily controlled by changing the raw materials ratio and calcination temperature. According to the results, N-doped SnOx/C anode material shows excellent stability (93.9% retention of the second cycle) and superior specific capacity (679.8 and 542.3 mAh g(-1) after 300 cycles at 200 mA g(-1) and 1000 mA g(-1), respectively). This strategy lights on the illuminating design of 3D carbon-coated Sn-based anode by liquid carbon source and commercial solid tin source, which can improve electrochemical performance for next-generation lithium-ion batteries.
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