期刊
JOURNAL OF POLYMERS AND THE ENVIRONMENT
卷 28, 期 1, 页码 116-122出版社
SPRINGER
DOI: 10.1007/s10924-019-01590-0
关键词
Adsorbent; Graft copolymerization; Cu2+ removal; Polyvinyl alcohol modification
资金
- National Natural Science Foundation of China [51674117, 21706059]
- Scientific Research Foundation of Hunan Provincial Education Department [18B354, 16K036,15B101]
- Natural Science Foundation of Hunan Province [2018JJ3211, 2018JJ3206]
Polyvinyl alcohol (PVA) hydrogel was crosslinked with glutaraldehyde. The crosslinked polyvinyl alcohol (CPVA) was grafted with acrylonitrile using cericammonium nitrate as an initiator (CPVA-PAN), and then modified by hydroxylamine hydrochloride (CPVA-AO-PAN). CPVA, CPVA-PAN, and CPVA-AO-PAN were characterized by Fourier Transform Infrared spectroscopy. Cu2+ adsorption by CPVA-AO-PAN reached the equilibrium at contact time of 40 h with a adsorption capacity of 40.7 mg g(-1). The effects of initial metal concentration, adsorption time, and pH on adsorption capacity were investigated, respectively. Pseudo-first-order and pseudo-second-order models were employed to evaluate the adsorption kinetics, with the R-2 values of 0.9524 and 0.9972, respectively. Langmuir and Freundlich isotherm models were compared, and the Langmuir model shows high goodness-of-fit. The adsorption process was endothermic and spontaneous, as evidenced by the positive increment H and the negative increment G.
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