期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 123, 期 50, 页码 30623-30632出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.9b09721
关键词
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资金
- Science and Engineering Research Board (SERB), New Delhi, India [EMR/2015/001535]
- CSIR, New Delhi, India [Chem.09/-013(0621)/2016EMR-I]
1,7-Phenanthroline based bis-boron dipyrromethenes (bis-BODIPYs) B1 and B2 obtained via small substitutional changes (-Cl/SCH3) have been described. The effect of restriction of intramolecular rotation (RIR) in emission enhancement in a viscous solvent (glycerol) has been studied besides the vital role of intermolecular interactions scrutinized by X-ray single-crystal studies. The efficiency of intersystem crossing (ISC) in the generation of singlet oxygen (Phi(Delta) similar to 19.2% and 56.7%) by photoirradiation using visible light along with distinct photostability has been investigated by 1,3-diphenylisobenzofuran (DPBF) titration studies. The O-1(2) generation quantum yield and photosensitizing durability of the bis-BODIPYs have been investigated by photooxidation of 1,5-dihydroxynaphthalene (DHN) in the presence of B1 and B2 as photosensitizers. The pseudo-first-order rate constants for photo-oxidation reactions and consumption rates of DHN reflected appreciable O-1(2) generation quantum yields (Phi(Delta): B1, 29.0; B2, 57.8%). Density functional theory (DFT) studies showed the distribution of electron density over the dipyrrin moiety. Overall results indicated that these new photosensitizers (PSs) may be very promising in photodynamic therapy of tumors, photobiology, and organic photochemistry.
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