期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 123, 期 45, 页码 27615-27627出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.9b08219
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资金
- US Department of Energy (DOE), Basic Energy Sciences (BES), Chemical, Sciences, Geosciences, and Biosciences (CSGB) Division, Geosciences program at University of Chicago [DE-FG02-94ER14466, DE-SC0019108]
- Argonne National Laboratory (ANL) [DE-AC02-06CH11357]
- National Science Foundation (NSF), Earth Sciences [EAR-1634415]
- ANL, a DOE Office of Science laboratory [DE-AC02-06CH11357]
- DOE Office of Science, Office of Basic Energy Sciences, Division of Materials Science and Engineering
- DOE [DE-AC05-76RL01830]
- NSF [1722969, 1541516]
- Directorate For Geosciences
- Division Of Earth Sciences [1541516] Funding Source: National Science Foundation
- Directorate For Geosciences
- Division Of Earth Sciences [1722969] Funding Source: National Science Foundation
- U.S. Department of Energy (DOE) [DE-SC0019108] Funding Source: U.S. Department of Energy (DOE)
The growth of aluminum (oxyhydr)oxide films on the basal surface of muscovite mica is an excellent model system for studying mineral nucleation, growth, and reactivity. Using off-specular crystal truncation rod X-ray scattering, we have determined the atomic-scale epitaxial relationships between muscovite and monolayer overgrowths of a gibbsite-like material. We observe that dioctahedral sheets of aluminum (oxyhydr)oxide grow in three structurally distinct domains, separated by antiphase boundaries. Vacancies in the dioctahedral sheets overlie either the silicate tetrahedra or the ditrigonal cavities of the underlying muscovite surface. High-resolution atomic force microscopy indicates lateral island sizes of similar to 10nm separated by 1-2 nm spaces. Together, the X-ray and microscopy data provide insights into the coordination chemistry and morphology of films formed by heterogeneous nucleation and growth.
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