期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 84, 期 22, 页码 14830-14843出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b02527
关键词
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资金
- DST-SERB, India [CRG/2018/000606]
- CSIR
The reaction of N-aryl acrylamides with maleimides in the presence of a ruthenium/rhodium catalyst and Cu(OAc)(2)center dot H2O provided succinimide-substituted oxindole derivatives in good to excellent yields. In the reaction, 3,3'-disubstituted oxindoles are produced via a C-H alkylation and intramolecular oxidative cyclization sequence. The proposed mechanism was supported by competition experiments, deuterium labeling studies, and radical scavenger experiments.
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