期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 387, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.jhazmat.2019.121702
关键词
Concentrated leachate; Dissolved organic matters; E+-ozonation; Reactive (non-) radical species; FT ICR-MS
资金
- National Natural Science Foundation of China [51678357, U1662128]
- National Key R&D Program of China [2018YFC1900704]
- Shanghai State-owned Assets Supervision and Administration Commission [2018001]
Concentrated leachate (CL) is commonly featured with high salt and dissolved organic matters (DOM). In this study, molecular transformation of DOM was revealed to identify the reactive mechanisms with (non-) radical reactive species in ozonation, electrolysis and E+-ozonation processes. Chlorine ions were efficiently activated into non-radical reactive chlorine species (RCS) with 245.7 mg/L, which was more dominant in electrolysis. Compared to ozonation, C-center dot OH was increased from 2.6 x 10(-4) mg/L into 5.8 x 10(-4) mg/L and the generation of Cl center dot/ClO center dot could be concluded according to the decline of non-radical RCS in E+-ozonation process. For chromophoric and fluorescent DOM, aromatic compounds and polymerization degree dramatically decreased in E+-ozonation. Lipid-like and CRAM/lignin-like compounds were substantially degraded, as center dot OH and ClO center dot/Cl center dot shows an affinity towards oxygen-containing organic compounds via single electron transfer by attracting O-H bonds. Especially, carbon/hydrogen/oxygen (CHO-containing) compounds were readily to be degraded with the removal efficiency of 92.5 %, 97.0 % and 98.4 % in electrolysis, ozonation and E+-ozonation, respectively. Moreover, nitrogen atoms have a negative effect on DOM degradation, and thus, carbon/hydrogen/nitrogen and carbon/hydrogen/nitrogen/sulfur (CHN- and CHNS-containing) compounds were considered as refractory compounds. This paper is expected to shed light on the synergetic effect in E+-ozonation and transformation of refractory DOM in CL treatment.
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