期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 554, 期 -, 页码 229-238出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2019.06.107
关键词
Photo-catalyst; Z-scherne hetero-junction; wO(3); SnS2
资金
- National Natural Science Foundation of China [51672215]
- Youth Innovation Team of Shaanxi Universities and Research Fund for the Doctoral Program of Higher Education of China (RFDP) [20136101110017]
An ideal photocatalyst not only offers high photo-generated electron-hole pairs separation ability, but also has suitable redox potential. Here, a direct Z-scheme core-shell structured WO3@SnS2 hetero-junction photo-catalyst was prepared via two-step hydrothermal method, in which the core-shell structure, rod morphology and micro-composition of hetero-junction were confirmed through X-ray diffraction (XRD) patterns, Fourier transform infrared (FTIR) spectra, field emission scanning electron microscope (FE-SEM), transmission electron microscope (FEI-TEM) and X-ray photoelectron spectra (XPS). Their enhanced photo-catalytic abilities were evaluated by photo-degradation of Rhodamine (RhB), photo-reduction of dichromate (Cr6+) solution and photo-catalytic H-2 production through comparing with pure WO3, SnS2 or the mixture of WO3 and SnS2 (WO3/SnS2). The absorption spectra and electrochemical properties were used to estimate the band gap of samples, the expanded spectral absorption capacity and improved electron-hole separation ability, which are important factors for enhanced photo catalytic performance. Furthermore, the direct Z-scheme charge transfer mechanism of WO3@SnS2 hetero-junction was determined through the combination of theoretical calculation and experimental characterizations, which played a decisive role for retaining excellent redox potential and increasing photo-catalytic ability of WO3 and SnS2. (C) 2019 Elsevier Inc. All rights reserved.
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