4.8 Article

Cobalt-molybdenum co-catalyst for heterogeneous photocatalytic H-mediated transformations

期刊

JOURNAL OF CATALYSIS
卷 379, 期 -, 页码 33-38

出版社

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2019.09.015

关键词

Molybdenum sulphide; Titanium dioxide; Heterogeneous photocatalysis; Semi-hydrogenation; Isomerization

资金

  1. Natural Sciences and Engineering Research Council of Canada
  2. Canada Foundation for Innovation
  3. Canada Research Chairs Program
  4. RISE program

向作者/读者索取更多资源

Earth abundant materials, Mo and Co, are used to decorate TiO2 and work as co-catalyst for the selective semi-hydrogenation of alkynes and isomerization of estragole in a H-2-free environment under UVA irradiation. Catalytic efficiency is higher than highly-reactive Pd-decorated TiO2, using lower metal loadings and showing better selectivity towards the semi-hydrogenation reaction. (C) 2019 Elsevier Inc. All rights reserved.

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