Comparison in composite performance after thermooxidative aging of injection molded polyamide 6 with glass fiber, talc, and a sustainable biocarbon filler

Degradation is an unavoidable part of a material's life making it important to both monitor and control the aging behavior of plastics. This study compares thermooxidative degraded composites of a novel bio-based and sustainable filler, Biocarbon (MBc), against that of traditional and commercially available fillers (glass fiber and talc) used in the automotive industry. The influence of thermooxidative degradation on the composites was studied under accelerated heat aging for 1000 h at 140 degrees C. The mechanical properties of the composites were evaluated using notched Izod impact as well as both tensile and flexural tests. Morphological structure of the composites was investigated using a scanning electron microscopy. Dynamic mechanical analysis and differential scanning calorimetry were used to evaluate the physical transitions both before and after aging. The glass-filled composites displayed the best performance; while, both the talc and biocarbon composites possessed similar strength and ductility performances. Advantageously, the biocarbon composites experienced an 11% reduction in density as compared to talc-filled composites with similar weight content. After aging, all composites exhibited reduced tensile and flexural strengths ranging from 5 to 67% partly due to chain scission. Whereas, the modulus of all composites increased with a range of 1-24% due to an annealing effect. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 137, 48618.