期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 810, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2019.151961
关键词
Supercapacitor; MOFs; N, S co-doping; Precursor; Pseudocapacitance
资金
- National Natural Science Foundation of China [21665024]
- Key Lab of Polymer Materials of Gansu Province
Nitrogen sulfur co-doped bimetal nanocomposites (NS-BNs) are prepared through vulcanization and annealing using bimetallic Ni/Co-MOF as a precursor. The nitrogen sulfur co-doped bimetal nanocomposites have abundant electroactive sites and redox reaction centres, which exhibit remarkable electrochemical performance as electrode materials for supercapacitor. The specific capacitance could reach 1529 F g(-1) at a current density of 1 A g(-1) and excellent cycle stability (retention rate of 89.29% after 10000 cycles). After the current density is expanded ten times, the specific capacitance can still reach 1069 F g(-1), indicating superior rate performance. Furthermore, the assembled asymmetric supercapacitor displayed a high energy density of 41.04 Wh kg(-1) at power density of 750 W kg(-1). As a result, non-metal doped nanocomposites material has promised applications for electrochemical supercapacitors. (C) 2019 Elsevier B.V. All rights reserved.
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