期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 806, 期 -, 页码 464-470出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2019.07.175
关键词
ZnO nanoparticles; Nitrogen-doped; Hierarchically porous carbon; Supercapacitor
资金
- National Natural Science Foundation of China (NSFC) [21606068]
- Natural Science Foundation of Tianjin City [17JCQNJC06300]
This paper reports on the synthesis of ZnO/nitrogen-doped hierarchically porous carbon (ZnO/N-OHPC) and its application as electrode for supercapacitor. N-OHPC having large surface area, 3D ordered macropores and ordered mesopores in the carbon skeleton is fabricated from dual-templates with dicyandiamide as the nitrogen source. Through a convenient in situ solution growth way, ultrafine ZnO nanoparticles (similar to 3.2 nm) are evenly distributed on the macroporous walls of N-OHPC. The as-synthesized ZnO/NeOHPC (38.6 wt% ZnO) exhibits a maximum gravimetric capacitance of 720 F g(-1) at 1 A g(-1) within the potential window of 0.1-0.5 V. In addition, it exhibits a great rate ability (66% capacitance retention at 10 A g(-1)) and durability (90% of the initial capacitance was obtained after 30,000 cycles). The superior electrochemical performance is due to the synergistic effects of small ZnO nanoparticles and N-doped ordered hierarchically porous carbon. (C) 2019 Elsevier B.V. All rights reserved.
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