期刊
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
卷 58, 期 47, 页码 21233-21241出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.iecr.9b04380
关键词
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资金
- National Nature Science Foundation of China [51572079, 51772090]
- Hunan Provincial Innovation Foundation for Postgraduate [CX2018B732]
Construction of reasonable nanostructures for electrode materials is regarded as one critical strategy for improving capacitance and cycle life of supercapacitors (SCs). Here, self-supported, sisal-like CuCo2O4@Ni(OH)(2) composites were successfully synthesized on Ni foam using a hydrothermal treatment followed by the electrochemical deposition reaction. Scanning electron microscopy characterization of the composites verified that the sisal-like CuCo2O4@Ni(OH)(2) core-shell nanostructure comprising coating CuCo2O4 nanoneedles with Ni(OH)(2) nanoflakes. This novel structure afforded the CuCo2O4@Ni(OH)(2) composites a markedly enhanced specific capacitance of 1902 F g(-1) at 2 A g(-1) and an ultralong cycle life with a captaincy retention of 87.6% after 50 000 cycles at 10 A g(-1). Furthermore, an asymmetric solid-state supercapacitor comprising CuCo2O4@Ni(OH)(2) //activated carbon was assembled and it exhibited a high energy density of 38.6 W h kg(-1) at 800 W kg(-1). These performances strongly suggest that the self-supported sisal-like CuCo2O4@Ni(OH)(2) electrode is a very promising positive material for use in SCs.
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