期刊
ENVIRONMENTAL SCIENCE & TECHNOLOGY
卷 53, 期 22, 页码 13417-13426出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.est.9b03687
关键词
-
资金
- National Natural Science Foundation [21677023]
- Research Project of Key Laboratory of Liaoning Provincial Education Department [LZ2015023]
Despite the increase in production, usage, and discharge of organophosphate flame retardants (OPFRs), little information is available about their bioaccumulation and trophic transfer in the marine food web. In this study, seawater, sediment, and marine species (10 fish and 9 invertebrate species) collected from Laizhou Bay, North China, were analyzed to investigate the levels, bioaccumulation, and biomagnification of OPFRs in a marine food web. Of 20 OPFRs screened for, 17 were quantifiable in seawater, sediment, and organisms. The Sigma OPFRs concentrations ranged from 0.2 to 28.4 ng/L in seawater, 0.1-96.9 ng/g dry weight in sediment, and 21.1-3510 ng/g lipid weight in organisms. Benthic fish accumulated more OPFRs than pelagic fish and invertebrates. A linear and significant increase of bioaccumulation factors with increasing lipophilicity of OPFRs was observed (R-2 = 0.63, p < 0.05), and the biota-sediment accumulation factors increased with hydrophobicity up to log K-OW = 4.59 and then decreased with increase in log K-OW. Trophic magnification factors of OPFRs ranged from 1.06 to 2.52, indicating biomagnification potential of OPFRs in a marine food web. This study provides important insight into the biomagnification potential of OPFRs and suggests further investigation on this group of chemicals.
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