期刊
ENVIRONMENTAL MONITORING AND ASSESSMENT
卷 191, 期 11, 页码 -出版社
SPRINGER
DOI: 10.1007/s10661-019-7893-2
关键词
Cluster analysis; Discriminant analysis; Factor analysis; Environmental impact
资金
- Coordenacao de Aperfeicoamento e Pessoal de Nivel Superior (CAPES) [001]
Weed control efficiency and the environmental contamination potential of herbicides depend on soil sorption and desorption. Among the indexes that evaluate the soil adsorption processes, the coefficients sorption (Kf(s)) and desorption (Kf(d)) obtained by Freundlich isotherms can provide accurate information about the behavior of an herbicide in the soil. The values of Kf(s) and Kf(d) of an herbicide vary according to the physicochemical characteristics of the soil, so it is possible to estimate these coefficients with high precision if good predictive mathematical models are constructed. Therefore, our objective aimed to evaluate the use of multiple regression models (MLR) associated with multivariate techniques to estimate the coefficient Kf(s) and Kf(d) for the hexazinone based on the chemical and physical attributes of soils. The correlation analyses, principal components, and clustering analysis allowed the multiple linear regression technique to generate models with higher adjustment coefficient (R-2) for Kf(s) (0.73 to 0.99) and Kf(d) (0.94 to 0.99), and lower root mean squared error (RMSE) for Kf(s) (0.003 to 0.065) and Kf(d) (0.018 to 0.120). Regression models created from groups of soils showed greater prediction performance for Kf(s) and Kf(d). The organic matter followed by the cation exchange capacity was the most important attributes of soils in sorption and desorption processes of hexazinone.
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