期刊
ELECTROCHIMICA ACTA
卷 321, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2019.134672
关键词
Negative electrode; Hollow structure; Long cycling; Structure design; Tin
资金
- National Natural Science Foundation of China [51602167, 21601098]
- Shandong Provincial Science Foundation [ZR2016EMB07, ZR2017JL021]
- Key Research and Development Program [2018GGX102033]
- Qingdao Applied Fundamental Research Project [16-5-1-92-jch, 17-1-1-81-jch]
- Distinguished Taishan Scholar project
Alloy-type materials hold a great potential as the negative electrodes for next generation lithium-ion batteries with high energy and low cost. However, the huge volume expansion of alloy-type materials caused by lithium alloying inevitably leads to poor cycle stability. Herein, we propose a rational design of a sandwich structure of carbon/Sn/carbon hollow spheres by a template-engaged method. The structure effect of the novel carbon/Sn/carbon spheres on the lithium storage performances is elucidated by various means of characterization and electrochemical tests. A stable and high reversible capacity of 1100 mA h g(-1) is retained after 130 cycles at 0.1 A g(-1), significantly higher than that (187 mA h g(-1) ) of Sn/carbon hollow spheres. Furthermore, a superior rate capability is obtained for carbon/Sn/carbon spheres, e.g., showing a high capacity of 430 mA h g(-1) at 5 A g(-1). The excellent electrochemical properties of carbon/Sn/carbon against Sn/carbon are ascribed to a unique nano-confinement from the double-shelled carbons with very good structure stability and contribution of pseudocapacitive storage of lithium. These results indicate that the sandwich structure of carbon/Sn/carbon is highly effective to design electrode materials with enhanced performances. (C) 2019 Published by Elsevier Ltd.
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