期刊
DIAMOND AND RELATED MATERIALS
卷 98, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.diamond.2019.107484
关键词
Carbon nanotubes; Nitrogen doping; Palladium; Isolated ions; Nanoparticles; Nitrobenzene hydrogenation
类别
资金
- Ministry of Science and Higher Education of the Russian Federation [AAAA-A17117041710084-2]
- Spanish MINECO under the Maria de Maeztu Units of Excellence Program [MDM-2016-0618]
The use of nitrogen doped carbon nanotubes (N-CNTs) as a palladium catalyst support resulted in the formation of isolated palladium ions and metal nanoparticles, depending on the Pd content. It was found that the formation of isolated palladium ions is due to the presence of pyridinic nitrogen centers in the N-CNTs and does not depend on the method of palladium deposition (impregnation or reductive deposition). These ions possess high thermal stability in hydrogen atmosphere, poorly adsorb CO even at subambient temperature and are low active in catalytic hydrogenation of nitrobenzene to aniline. The beneficial role of the N-CNTs was found to be in the stabilization by graphitic nitrogen of the metallic Pd nanoparticles of similar to 1.5 nm size showing high activity towards aniline formation at atmospheric pressure. The possibility of the tailored synthesis of different metal species by means of the N-CNTs as a support opens a wide room for use of these carbon nanomaterials in various catalytic applications.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据