期刊
CORROSION SCIENCE
卷 159, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2019.108161
关键词
Refractory high entropy alloy; High temperature corrosion; Compositionally complex alloy; Quartic rate law; CrTaO4 formation
资金
- Deutsche Forschungsgemeinschaft (DFG) [GO 2283/4-1, GO 2283/2-1]
The high-temperature oxidation mechanism of a series of refractory high entropy alloys: TaMoCrTiAl, NbMoCrTiAl, NbMoCrAl and TaMoCrAl at 1000 degrees C in air was studied. A complex protective oxide layer consisting of Al2O3, Cr2O3 and CrTaO4 oxides was observed for the quinary Ta-containing alloy. The formation of CrTaO4 in this alloy after a short incubation period decreased the oxidation kinetics from a parabolic to a quartic rate law. Ti was found to support the formation of CrTaO4. In the Nb-containing alloys, the formation of different Nb2O5 polytypes near the metal/oxide interface caused a highly porous oxide scale and severe oxide spallation.
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