期刊
COMPOSITES PART B-ENGINEERING
卷 176, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.compositesb.2019.107078
关键词
Graphene oxide; Carbon fibers; Polymer-matrix composites; Interfacial strength
资金
- Natural Science Foundation of China [51803102]
- Project of China Postdoctoral Science Foundation [2017M612196, 2017M612197]
To improve the dispersion of graphene oxide (GO) nanosheets in sizing agent and to enhance the interfacial adhesion between GO and epoxy, GO nanosheets were chemically modified with cyanuric chloride (TCT) and diethylenetriamine (DETA). The functionalized GO (i.e. GO-TCT-DETA) with different contents was introduced into the carbon fiber (CF) interface by sizing process. The uniform distribution of GO sheets on CF surface and the enhancement of surface roughness were obtained. Moreover, significant enhancements (i.e., 104.2%, 100.2%, and 78.3%) of interfacial shear strength (IFSS), interlaminar shear strength (ILSS), and flexural properties were achieved in the composites with only 1.0 wt% GO-TCT-DETA sheets introduced in the fiber sizing. The GO-TCT-DETA in the interface region enhanced the stress being transferred effectively and the local stress concentrations being relieved. This study indicates that the utilization of functionalized GO is one of the alternative approaches for controlling the fiber-matrix interface and improving the mechanical properties of CF epoxy composites.
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