期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 25, 期 71, 页码 16214-16218出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201903789
关键词
bioinorganic chemistry; caged nucleosides; metal-mediated base pairs; nucleic acids; thymidine
资金
- Westfalische Wilhelms-Universitat Manster
By applying caged thymidine residues, DNA duplexes were created in which Hg-II-mediated base pair formation can be triggered by irradiation with light. When a bidentate ligand was used as the complementary nucleobase, an unprecedented stepwise formation of different metal-mediated base pairs was achieved.
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