期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 26, 期 4, 页码 853-862出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201903893
关键词
doping; electrochemistry; lithium storage; micro; nanoengineering; N-doped carbon shells; alpha-Fe2O3
资金
- National Natural Science Foundation of China [21573036, 21873018]
- Education Department of Jilin Province [111099108]
- Fundamental Research Funds for the Central Universities [2412017FZ013, 2412019QD013]
- Open Project Program of the Key Laboratory for Biomedical Effects of Nanomaterials and Nanosafety, Chinese Academy of Science [NSKF201807]
The Fe-based transition metal oxides are promising anode candidates for lithium storage considering their high specific capacity, low cost, and environmental compatibility. However, the poor electron/ion conductivity and significant volume stress limit their cycle and rate performances. Furthermore, the phenomena of capacity rise and sudden decay for alpha-Fe2O3 have appeared in most reports. Here, a uniform micro/nano alpha-Fe2O3 nanoaggregate conformably enclosed in an ultrathin N-doped carbon network (denoted as M/N-alpha-Fe2O3@NC) is designed. The M/N porous balls combine the merits of secondary nanoparticles to shorten the Li+ transportation pathways as well as alleviating volume expansion, and primary microballs to stabilize the electrode/electrolyte interface. Furthermore, the ultrathin carbon shell favors fast electron transfer and protects the electrode from electrolyte corrosion. Therefore, the M/N-alpha-Fe2O3@NC electrode delivers an excellent reversible capacity of 901 mA h g(-1) with capacity retention up to 94.0 % after 200 cycles at 0.2 A g(-1). Notably, the capacity rise does not happen during cycling. Moreover, the lithium storage mechanism is elucidated by ex situ XRD and HRTEM experiments. It is verified that the reversible phase transformation of alpha <->gamma occurs during the first cycle, whereas only the alpha-Fe2O3 phase is reversibly transformed during subsequent cycles. This study offers a simple and scalable strategy for the practical application of high-performance Fe2O3 electrodes.
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