期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 26, 期 14, 页码 2985-2992出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201904419
关键词
giant molecules; isomers; macromolecules; self-assembly; topology
资金
- National Natural Science Foundation of China [21674003, 91427304]
- National Key R&D Program of China [2018YFB0703702]
- Peking University
Macromolecular isomerism has been an important yet largely understudied subject. Giant molecules based on molecular nanoparticles exhibit properties highly dependent on the primary structures, providing a platform for such studies. Various isomers have been designed, synthesized and characterized, including sequence-, regio-, and topo-isomers. The self-assembly of these isomers is influenced by the distinct symmetry and collective interaction of each building block in a subtle and delicate way. The results suggest that isomerism may be exploited as a new way for fine-tuning the structures and properties of macromolecules, which should be of great interest in both fundamental research and technical innovation.
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