期刊
CHEMICAL ENGINEERING JOURNAL
卷 384, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2019.123327
关键词
FeSb alloy; N-doped porous carbon; Anode; Potassium/sodium ion battery
资金
- National Natural Science Foundation of China [51871046, 51902046, 51874079, 51571054, 51771046, 51674068]
- Natural Science Foundation of Liaoning Province [201602257]
- Natural Science Foundation of Hebei Province [E2019501097, E2018501091]
- Science and Technology Project of Hebei Province [15271302D]
- Training Foundation for Scientific Research of Talents Project Hebei Province [A2016005004]
- Young Talents Program in University of Hebei Province [BJ2018014]
- Hebei Province higher education science and technology research project [QN2017103]
- Fundamental Research Funds for the Central Universities [N182304017, N182304015, N172302001, N172304044]
Sb-based anodes have shown great potential in sodium-ion batteries (SIBS) and potassium-ion batteries (PIBs) owing to their high theoretical capacities and applicable voltage platforms, but they usually suffer from severe volume change and sluggish ion diffusion kinetic. Herein, a novel N-doped three-dimension porous carbon network confined nanosized FeSb alloy composite (3D FeSb@NC) with a strong Fe-N-C bond is elaborately designed and fabricated, this unique structure sufficiently relieves the volume change of Sb during cycling, reduces the diffusion length for both ion/electrons, enhances the electronic conductivity, and provides abundant active sites for Na+/K+ storage. Moreover, the strong Fe-N-C bond can strengthen the interface adhesion between carbon matrix and alloy particle for sustaining structure integrity. The 3D FeSb@NC anodes delivers outstanding electrochemical performances in both SIBS and PIBs, in terms of ultralong cycling life (capacity retention of 85% after 750 cycles for SIBS and 80% after 1000 cycles for PIBs) and excellent rate capability (231 mAh g at 5 A g(-1) for SIBS and 119.7 mAh g at 2 A g(-1) for PIBs). The kinetic analysis of Na+/K+ storage reveal that the extrinsic pseudo-capacitive contribution accounts for the high rate performance. This work provides an effective strategy to develop nanocomposite anode with superior structural stability and durability for SIBS/PIBs.
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