期刊
CHEMICAL ENGINEERING JOURNAL
卷 375, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2019.122112
关键词
Isotherm types; Hysteresis; Generalized van der Waals; Square-well potential; Adsorption
资金
- State of Wyoming
- Department of Energy [DE-PI0000017]
A new adsorption model is proposed based on the Generalized van der Waals partition function by introducing the concept of attractive region, which integrates the effects of the adsorption sites of adsorbent and represents pore space where adsorbates concentrate. A theoretical expression for the chemical potential of adsorbates in the attractive region is derived and used to calculate the adsorbate density in each attractive region. The model can generate all the six types of isotherms classified by the International Union of Pure and Applied Chemistry (IUPAC) report including those with hysteresis and is easy to use. It is a generalized model that can be applied to various types of porous materials. With the fitted parameters, the model can predict the adsorption isotherms even for adsorbents with wide pore size distributions. It also well captures the isotherm-type transition as temperature changes and can estimate the hysteresis when capillary condensation exists.
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