期刊
CHEMICAL ENGINEERING JOURNAL
卷 373, 期 -, 页码 1144-1157出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2019.05.069
关键词
Photocatalysis; Direct dual Z-scheme; Ternary heterojunction; Antibiotics; g-C3N4/Bi2WO6/AgI
资金
- Hunan Provincial Innovation Foundation For Postgraduate [CX2018B196]
- Program for the National Natural Science Foundation of China [51879101, 51579098, 51779090, 51709101, 51521006, 51809090, 51278176, 51378190]
- National Program for Support of Top-Notch Young Professionals of China (2014)
- Program for Changjiang Scholars and Innovative Research Team in University [IRT-13R17]
- Hunan Provincial Science and Technology Plan Project [2018SK20410, 2017SK2243, 2016RS3026]
- Fundamental Research Funds for the Central Universities [531119200086, 531118010114, 531107050978]
A novel direct dual Z-scheme g-C3N4/Bi2WO6/AgI (CBA) ternary heterojunction photocatalyst was fabricated through the hydrothermal reaction and a succedent in-situ precipitation route for the first time. Systematic studies showed that the 20% AgI and 60% g-C3N4 co-modified Bi2WO6 presented the highest photocatalytic performance, achieving 91.13% removal efficiency of tetracycline within 60 min, which was 10.04 times that of pure Bi2WO6. The enhanced photocatalytic performance mainly derived from the co-effects of Bi2WO6, g-C3N4 and AgI and could be summarized as following: i) The g-C3N4 nanosheets could be used as carriers for dispersion of Bi2WO6 and AgI nanoparticles, preventing their agglomeration; ii) The addition of g-C3N4 and AgI could promote the light absorption, resulting in the strengthened light harvesting ability; iii) The intimate contact of Bi2WO6, g-C3N4, and AgI favored the separation and transfer of photogenerated carriers. Further analysis demonstrated that the path of photogenerated electrons moved exhibited a direct dual Z-scheme pattern in ternary heterojunction, which not only fulfilled the efficient spatial separation of photogenerated electron-hole pairs but also endowed the composites with strong redox capability, thereby boosting the photodegradation efficiency of CBA composite. This work opens a new strategy to constructing multi-component Z-scheme photocatalytic system for environmental decontamination.
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