期刊
CHEMICAL ENGINEERING COMMUNICATIONS
卷 208, 期 6, 页码 812-821出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/00986445.2019.1680370
关键词
Crystallinity; Dehydroxylation; Minerals; Moisture content; Specific heat capacity; Thermal dehydration
This study evaluated the potential of FTIR spectroscopy and thermal analytical techniques for analyzing the mineralogical and organic matter framework of soils in the Anaimalai region of Tamil Nadu, India. The results indicated higher disorder in agricultural soils compared to forest soils, and the feasibility of thermal analysis techniques in identifying certain minerals not detected by FTIR spectroscopy. Additionally, differential scanning calorimetry showed that forest soils have higher moisture content, indicating better water retention capacity.
The present study assesses the potential usefulness of Fourier transform infrared spectroscopy (FTIR) spectroscopy and thermal analytical techniques to elucidate the mineralogical and organic matter (OM) framework of soils from Anaimalai situated in Coimbatore district, Tamil Nadu, India. Soil samples were procured from forests (AF1-AF3), agricultural land (AA1-AA3), and road side areas (AR1-AR3) along Anaimalai-Valparai region by random sampling method. FTIR spectra revealed the presence of silicates (quartz, orthoclase and microcline feldspars, kaolinite clay minerals), carbonates, and OM (organic carbon and humus) in the soils. The values of crystallinity index determined from FTIR were larger than one for all soils indicating that minerals in soils are highly disordered, with agricultural soils exhibiting slightly high disorderedness. From prior literature studies, it is known that only few seminal studies have highlighted the importance of application of thermal analytical techniques to soils. The present work demonstrates the feasibility of usage of differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), in identifying the minerals smectite, calcite, and dolomite that could not be identified by FTIR spectroscopy. Specific heat capacities (C-p) of soils were determined from DSC and it can be inferred from the results that forest soils contain higher moisture content which in turn is indicative of good water retention for a healthy forest. Thus, the feasibility of various analytical techniques for soil analysis has been demonstrated.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据