期刊
APPLIED SURFACE SCIENCE
卷 493, 期 -, 页码 193-201出版社
ELSEVIER
DOI: 10.1016/j.apsusc.2019.07.001
关键词
Pervaporation; Halloysite nanotube; Polyvinyl alcohol; Polyvinyl amine; Surface modification
类别
资金
- New & Renewable Energy Core Technology Program of the Korea Institute of Energy Technology Evaluation and Planning (KETEP)
- Ministry of Trade, Industry and Energy of the Republic of Korea [20194010201840, 20172010106170]
- Korea Institute of Energy Technology Evaluation and Planning (KETEP)
- Korea Evaluation Institute of Industrial Technology (KEIT) [20172010106170] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Surface modification of a halloysite nanotube (HNT) was performed by piranha etching of the HNT surface to generate hydrophilic moiety on the surface. The HNT and surface-modified HNT (MHNT) were embedded in polyvinyl alcohol/polyvinyl amine (PVA/PVAm) membranes. Surface modification of the HNT was confirmed using X-ray photoelectron spectroscopy, Fourier transform infrared, and transmission electron microscopy analyses. The 5 wt% MHNT-embedded membrane showed the best pervaporation performance (flux = 0.13-0.031 kg/m(2) h and separation factor = 427-93,313) among all membranes at 40 degrees C with 80-90 wt % of isopropanol (IPA) in the feed solution. Up to 5 wt% loading of HNT and MHNT in the membrane, the flux decreased, while the separation factor increased and subsequently decreased continuously with further HNT and MHNT loading. This was attributed to the hydrophilicity arising from HNT inclusion in the membranes. The membrane performance was evaluated under various pervaporation-operating conditions. Based on the solution diffusion model, with increase in water content, flux increased, while separation factor decreased. The temperature dependence of flux followed the Arrhenius equation. The energy of activation for the permeation of water (25.99 kJ/mol) was less than that of IPA (143.49 kJ/mol for the 5 wt% MHNT-loaded membrane at an 85 wt% of feed IPA composition). Overall, the pervaporation data suggested that the presence of MHNT in the PVA/PVAm membrane benefited pervaporation dehydration.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据