期刊
APPLIED SURFACE SCIENCE
卷 492, 期 -, 页码 792-807出版社
ELSEVIER
DOI: 10.1016/j.apsusc.2019.06.198
关键词
Stainless steel; Bicarbonate/carbonate; Passivation; Surface chemistry; Passive film
类别
资金
- National Natural Science Foundation of China [51701102, 51601182]
- Fundamental Research Funds for the Central Universities [201762008]
- National Environmental Corrosion Platform
Passivation behavior and surface chemistry of 304 stainless steel in alkaline solution with different HCO3(-)/ CO32- concentrations are studied with a combined electrochemical and XPS analytical investigation. Cathodic and anodic reactions are inhibited and accelerated, respectively, attributed to the depletion of acceptable oxygen and variation of passive film properties. Increasing HCO3(-)/ CO32- concentration does not alter the bilayer structure but leads to an intensification in electric field strength and composition changes including enrichment of oxidized Cr, increase of Fe(II)/Fe(III) ratio, and decrease of OH-/O2- ratio of the film. Meanwhile, the film thickness is reduced and the point defect density is increased due to the enhanced film dissolution. High HCO3-/CO32- concentration increases the critical chloride concentration of 304 SS in alkaline solution, attributed to the inhibition of the localized acidification within the pits and suppression of the stable pit development.
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