期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 256, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.apcatb.2019.117820
关键词
Internal microelectrolysis-Fenton; Montmorillonites; Fenton reaction; Phenol; Methyl orange
资金
- National Key Research and Development Program of China [2016YFA0203100]
- National Natural Science Foundation of China [21537004, 21777169, 21621064]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB14010201]
Core/shell type Fe-0@carbon (Fe@C) nanocomposites inserted in the interlayer space of montmorillonites (MMT) is prepared by one-step pyrolysis of Fe-metal organic frameworks and MMT. Fe@C-MMT serves as Fenton-like catalyst to degrade organic pollutants based on internal microelectrolysis (IME)-Fenton reactions. The MMT coat accelerates galvanic corrosion of Fe-0 to facilitate in-situ generation of Fe2+ and achieves self-regulation of solution pH. Strengthened elimination of phenol and methyl orange with high mineralization efficiency (80%) at initial pH 3-6.5 was achieved in Fe@C-MMT-H2O2 system compared to Fe@C-, ZVI-, and commercial Fe-C-H2O2 systems. The MMT coat retards contact of Fe-0 and Fe(II) species on Fe@C-MMT surface with H2O2, leading to rate-controlling consumption of H2O2 to keep the long-lasting efficiency of the IME-Fenton system. Fe@C-MMT suspension with 10 mM of H2O2 can continuously degrade organic pollutants within 40 h. Fe@C-MMT can be recycled for five times and shows good resistance to oxygen and acid corrosion.
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