期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 268, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.apcatb.2019.118413
关键词
Electrochemical catalysis; Low concentration coal mine methane; Solid oxide fuel cell; Heterogeneous kinetics
资金
- National Natural Science Foundation of China [51602343]
- Natural Science Foundation of Jiangsu Province [BK20160271]
- China Postdoctoral Science Foundation [2016M600449, 2019T120481]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT17R103]
- Program of Introducing Talents of Discipline to Universities [B17041]
- Program for Innovation Research Team of CUMT [2015QN004]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
Large quantity of low-concentration coal mine methane (LC-CMM) has been directly emitted to the air, causing severe greenhouse effect and energy loss. We propose to convert the pollutant gas to clean energy by the anodic electrochemical catalysis of solid oxide fuel cells. In the electrochemical conversion of oxygen-bearing LC-CMM, the Ni-based anode shows high catalytic activity and good stability without severe carbon deposition, Ni oxidation or thermal runaway. High electrochemical performance and good discharging stability were achieved with very flexible O-2/CH4 ratio and low CH4 concentration. The high electric efficiency of 38.2 % with the fuel utilization of 72 % and the stable discharging for 400 h can be realized by the stacks using the LC-CMM. Accordingly, a heterogeneous kinetics and electrochemical charge-transfer model was established to study the elementary reaction mechanism of O-2 in CH4 conversion and carbon removing, also showing the theoretical thresholds of coking and Ni oxidation.
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