期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 254, 期 -, 页码 677-684出版社
ELSEVIER
DOI: 10.1016/j.apcatb.2019.05.027
关键词
Heterogeneous photocatalysis; Metal-organic frameworks; MIL-125(Ti)-NH2; Metal nanoparticles; Overall water splitting
资金
- Spanish Ministry of Economy and Competitiveness [CTQ2015-69163-CO2-R1]
- Generalitat Valenciana [2017-083]
- Research Executive Agency (REA)
- European Commission [709023/ ZESMO]
- Fundacion Ramon Areces (XVIII Concurso Nacional para la Adjudicacion de Ayudas a la Investigacion en Ciencias de la Vida y de la Materia, 2016)
- Electron Microscopy Service facility at Universitat Politecnica de Valencia
Titanium containing aminoterephthalate metal organic framework promotes the photocatalytic overall water splitting into H-2 and O-2 at a rate that depends on the presence of Pt, RuOx and CoOx co-catalyst. The best values of have been obtained for the MIL-125-NH2 material that contains Pt and RuOx, reaching a production of 218 and 85 mu mol/g (-1)(photocataly)(st) at 24 h for H-2 and O-2, respectively.
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