期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 50, 页码 18154-18158出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201911268
关键词
asymmetric catalysis; C-H activation; chiral carboxylic acid; quinoline; rhodium
资金
- JSPS KAKENHI [JP15H05802, JP18H04637, JP17H03049, JP19K16306]
Catalytic enantioselective directed methylene C(sp(3))-H amidation reactions of 8-alkylquinolines using a Cp*Rh-III/chiral carboxylic acid (CCA) hybrid catalytic system are described. A binaphthyl-based chiral carboxylic acid efficiently differentiates between the enantiotopic methylene C-H bonds, which leads to the formation of C-N bonds with good enantioselectivity.
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