Engineering Surface Patterning of Colloidal Rings through Plateau-Rayleigh Instability

Plateau-Rayleigh (P-R) instability occurring on Brownian colloidal particles is presented. This instability can be used for the surface patterning of Brownian colloidal rings. This idea was realized by employing polystyrene(PS)/SiO2 core/shell rings, for which PS layer was selectively grown onto the interior surface of SiO2 rings. The P-R instability was initiated in the ring's dispersion by adding a good solvent of PS. By using both experiments and theory, it is shown that the number of patches is tunable and that it is linearly related to a function of two variables, namely, solvent quantity and contact angle. In particular, one-patch Janus rings and patchy disks were also synthesized at high yields. The patch size of all particles is tunable by step-by-step polymerization and the patches can be functionalized, for example by ATRP grafting with pH-sensitive polymers. This approach can be adapted for the synthesis of other patchy colloids with designated complexity.