期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 44, 页码 15640-15645出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201909457
关键词
C-H activation; density functional calculations; oxidative catalysis; reaction mechanisms; ruthenium
资金
- DFG [SPP1807]
- DFG (Gottfried-Wilhelm-Leibniz award)
Experimental and computational studies provide detailed insight into the selectivity- and reactivity-controlling factors in bifurcated ruthenium-catalyzed direct C-H arylations and dehydrogenative C-H/C-H functionalizations. Thorough investigations revealed the importance of arene-ligand-free complexes for the formation of biscyclometalated intermediates within a ruthenium(II/IV/II) mechanistic manifold.
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