期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 48, 页码 17251-17254出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201910197
关键词
C-H activation; indium; metalloligands; rhodium; Z-type ligands
资金
- JSPS KAKENHI [15H05800, 17H03019, 18H04646]
- JST, PRESTO, Japan [JY290145]
- Grants-in-Aid for Scientific Research [18H04646, 17H03019] Funding Source: KAKEN
Rhodium complexes with an indium metalloligand were successfully synthesized by utilizing a pyridine-tethered cyclopentadienyl ligand as a support for an In-Rh bond. The indium metalloligand dramatically changes the electronic and redox properties of the rhodium metal, thereby enabling catalysis of sp(2)C-H bond activation.
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