期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 40, 页码 14374-14378出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201908553
关键词
flow chemistry; microreactors; photochemistry; solar energy; synthetic methods
资金
- European Union [641861]
- Marie Curie European post-doctoral fellowship (MOSPhotocat) [793677]
- Max Planck Society
- DFG InCHeM [FOR 2177]
- Marie Curie Actions (MSCA) [793677] Funding Source: Marie Curie Actions (MSCA)
The sun is the most sustainable light source available on our planet, therefore the direct use of sunlight for photochemistry is extremely appealing. Demonstrated here, for the first time, is that a diverse set of photon-driven transformations can be efficiently powered by solar irradiation with the use of solvent-resistant and cheap luminescent solar concentrator based photomicroreactors. Blue, green, and red reactors can accommodate both homogeneous and multiphase reaction conditions, including photochemical oxidations, photocatalytic trifluoromethylation chemistry, and metallaphotoredox transformations, thus spanning applications over the entire visible-light spectrum. To further illustrate the efficacy of these novel solar reactors, medicinally relevant molecules, such as ascaridole and an intermediate of artemisinin, were prepared as well.
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