期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 362, 期 1, 页码 133-138出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201901392
关键词
semicarbazide; transient directing group; 2-methylbenzaldehyde; 2-benzylbenzaldehyde
资金
- National Natural Science Foundation of China [21462038]
Semicarbazide as an effective transient directing group for C(sp(3))-H arylation of 2-methylbenzaldehydes is described. Various substituted 2-benzylbenzaldehydes are efficiently synthesized by this strategy. The salient features of this protocol are the use of inexpensive transient directing group, wide scope of substrates with good functional group compatibility, up to 98% yield, and applicability to gram scale.
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