期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 361, 期 22, 页码 5239-5244出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201900953
关键词
Arylazo Sulfones; Photocatalyst-Free Reactions; Aryl Radical; Arbuzov Reaction; Photochemistry
A visible light-induced formation of Aryl-Phosphorous bonds starting from arylazo sulfones and triaryl (or trialkyl)phosphites in the absence of any photoredox catalyst and any additives was developed. This reaction showed a broad substrate scope and afforded (hetero)aryl phosphonates in good yields and in up to the gram scale.
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