期刊
ACS APPLIED MATERIALS & INTERFACES
卷 11, 期 49, 页码 46062-46069出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.9b14763
关键词
non-Cd blue emitters; alloyed ZnSeTe quantum dots; ZnSe inner shell; quantum dot light-emitting diode; external quantum efficiency
资金
- National Research Foundation of Korea (NRF) - Ministry of Science, ICT & Future Planning (MSIP) [2017R1A2B3008628, 2018M3D1A1058536, 2015M3D1A1069755]
- Basic Science Research Program through the NRF - Ministry of Education [2015R1A6A1A03031833]
- Korea Institute of Energy Technology Evaluation and Planning (KETEP)
- Ministry of Trade, Industry Energy (MOTIE) [20163030013980]
Considering a strict global environmental regulation, fluorescent quantum dots (QDs) as key visible emitters in the next-generation display field should be compositionally non-Cd. When compared to green and red emitters obtainable from size-controlled InP QDs, development of non-Cd blue QDs remains stagnant. Herein, we explore the synthesis of non-Cd, ZnSe-based QDs with binary and ternary compositions toward blue photoluminescence (PL). First, the size increment of binary ZnSe QDs is attempted by a multiply repeated growth until blue PL is attained. Although this approach offers a relevant blue color, excessively large-sized ZnSe QDs inevitably entail a low PL quantum yield. As an alternative strategy to the above size enlargement, the alloying of high-band gap ZnSe with lower-band gap ZnTe in QD synthesis is carried out. These alloyed ternary ZnSeTe QDs after ZnS shelling exhibit a systematically tunable PL of 422-500 nm as a function of Te/Se ratio. Analogous to the state-of-the-art heterostructure of InP QDs with a double-shelling scheme, an inner shell of ZnSe is newly inserted with different thicknesses prior to an outer shell of ZnS, where the effects of the thickness of ZnSe inner shell on PL properties are examined. Double-shelled ZnSeTe/ZnSe/ZnS QDs with an optimal thickness of the ZnSe inner shell are then employed for all-solution processed fabrication of a blue QD light-emitting diode (QLED). The present blue QLED as the first ZnSeTe QD-based device yields a peak luminance of 1195 cd/m(2), a current efficiency of 2.4 cd/A, and an external quantum efficiency of 4.2%, corresponding to the record values reported from non-Cd blue devices.
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