期刊
PROCESSES
卷 7, 期 10, 页码 -出版社
MDPI
DOI: 10.3390/pr7100652
关键词
1,10-phenanthroline; ethylenediaminetetraacetic acid; intrinsic reactivity; material selection; quality control; zero-valent iron
资金
- Ministry of Science and Technology of China through the Program Research on Mechanism of Groundwater Exploitation and Seawater Intrusion in Coastal Areas [20165037412]
- Ministry of Education of China through the Fundamental Research Funds for the Central Universities [2015B29314]
- Jiangsu Provincial Department of Education [2016B1203503]
- Postgraduate Research & Practice Innovation Program of Jiangsu Province [SJKY19_0519, 2019B60214]
There is a burgeoning interest in reliably characterizing the intrinsic reactivity of metallic iron materials (Fe-0) or zero-valent iron materials (ZVI) used in the water treatment industry. The present work is a contribution to a science-based selection of Fe-0 for water treatment. A total of eight (8) granular ZVI materials (ZVI1 to ZVI8) were tested. Fe-0 dissolution in ethylenediaminetetraacetic acid (EDTA test) and 1,10-Phenanthroline (Phen test) is characterized in parallel experiments for up to 250 h (10 days). 50 mL of each solution and 0.1 g of each Fe-0 material are equilibrated in quiescent batch experiments using 2 mM EDTA or Phen. Results indicated a far higher extent of iron dissolution in EDTA than in Phen under the experimental conditions. The tested materials could be grouped into three reactivity classes: (i) low (ZVI4, ZVI6, ZVI7, and ZVI8), (ii) moderate (ZVI1 and ZVI5) and (iii) high (ZVI2 and ZVI3). The order of reactivity was the same for both tests: ZVI2 ZVI3 > ZVI1 ZVI5 > ZVI4 ZVI6 ZVI7 ZVI8. Phen results revealed for the first time the time-dependent variation of the kinetics of iron corrosion (corrosion rate) in short-term batch experiments. Overall, the results demonstrated the superiority of the Phen test for evaluating the initial stage of Fe-0 dissolution. Long-term column experiments are recommended to deepen the acquired knowledge.
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