期刊
CHEMISTRYSELECT
卷 4, 期 29, 页码 8554-8557出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201901598
关键词
TAPC; hydrogen peroxide; sulfonyl chloride; Sulfonamides; oxidative chlorination
资金
- Research Council of Razi University
H2O2 in the presence of TAPC (1,3,5-triazo-2,4,6-triphosphorine-2,2,4,4,6,6-chloride) as an effective and chemoselective reagent system is described for the direct conversion of thiols to sulfonyl chlorides. Upon reaction with amines, the desired sulfonamides were produced in excellent yields and in short reaction times. Mild conditions, metal-free process, and excellent selectivity are some of the advantages of this method.
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